I print directly from the raw file.
I have photoshop CS4, I open my raw files in camera raw, I adjust them if needed, and from camera raw I open them in photoshop. I print them from photoshop without saving them in JPEG or Tiff.
If you've moved the image from ACR to Photoshop, you're no longer working with the raw file. ACR renders it to a TIFF behind the scenes, and that's what you're working with and then printing from in Photoshop
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